How to Transfer Song from iPod to Computer and iTunes Music Library
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Step 1: Download Tansee iPod Transfer then install it.
Get free trial version here.
Step 2: Connect iPod to your computer.
Step 3: Launch Tansee iPod Transfer and all the content of your iPod, including music and videos will display automatically, screenshot as follows:

Step 4: Select the files to be transferred to your computer by click them. Ctrl key for multi-files select. Click right button of your mouse can select all songs.
Note: you can only select first 5 songs if you haven't purchase.
Step 5: Click "Copy" button to select output path and start to transfer songs or videos to your computer:

How to Transfer Song from iPod to iTunes Music Library?
Step 1: Transfer your songs / videos to a folder on your computer by Tansee iPod Transfer, e.g. "C:/music" .
Step 2: Run iTunes, click "File", click "Add Files to Library..." or "Add Folder to Library..." , select the songs in folder C:/music.
Or simply run iTunes, Drag your files in "C:/music" to your iTunes music Library.